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Kulkarni, J. A m . Chem. , 1981, 103,6251. G. De Chirico, V. Fiandanese, G. Marchese, F. Naso, and 0. Sciacovelli, J. Chem. , Chem. , 1981,523. g. 70 The choice of starting materials from which the cuprates are generated, as well as the incorporation of an excess of lithium bromide, is important if dimerization of the intermediate vinylcuprates is to be avoided. g. g. 71 one cyclopentene the thermodynamically most stable isomer predominates. ~~ Scheme 28 70 ” ” ” 74 H. Westmijze, H. Kleijn, J. Meijer, and P.

C. Shih and J. S. , 1981, 22,4217. g. 12' Reagents: i, 3NaH or 3NaOEt; ii, R'CHBrC0,H; iii, R2CHO; iv, H 2 0 Scheme 44 HO. A x o % R CO,H (X= H or CH20H) Reagents: i, H2NCMe2CH20H;ii, HCHO-KOH; iii, H' Scheme 45 '16 'I7 120 G. A. Russell, B. Mudryk, and M. Jawdosiuk, Synthesis, 1981,62. D. Liotta, C. Barnum, R. Puleo, G. Zima, C. Bayer, and H. S. Kezar, 111, J. Org. , 1981, 46, 2920;D. Saindane, C. Barnurn, H. Ensley, and P. , 1981,22,3043. R. Antonioletti, M. D'Auria, G. Piancatelli, and A. , 1981,22, 1041.

K. Hatanaka, S. Tanimoto, T. Oida, and M. , 1981,22, 5195. Jabri, A. Alexakis, and J. F. Normant. , 1981,22, 959. '" The (hydroxymethy1)allyl sulphones (137) react stereoselectively with tri-nbutyltin hydride in the presence of a radical initiator to give allyltin derivatives 178 179 N. Miyaura, H. Suginome, and A. , 1981, 22, 127. M. Moreno-Mafias and A. , 1981, 22,3109. D. Jieh Shyh Tsai and D. S. , 1981,22, 2751. General and Synthetic Methods 40 (138) of mainly 2-configuration. 18' Reagents: i, RCHO; ii, (HOCH,CH,),N; iii, H,SO,; iv, KH R R H O A + ii S02Tol .

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A review of the literature published during 1981 by Frank Northen Magill

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